conformational properties and the anomeric effect study of phosphinanes

Document Type: Original Paper

Authors

1 Department of chemistry, Science and Reaserch branch, Islamic azad university, Tehran, Iran

2 Department of chemist r,y Mahshahr branch, Islamic azad university, Mahshahr, Iran

Abstract

Ab initio HF/6-31G* Methode was employed to calculate the bond length in 2- phosphinanes when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2- boromo substituented phosphinanes. The effect of anomeric effect have been effected on the bond length in 2-phosphinanes.

Keywords

References

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International Journal of Heterocyclic Chemistry

Volume 4, Issue 2
Summer 2014
Pages 25-32

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